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I have a 115AH deep-cycle battery that I bought as a stand-by battery for
my amateur radio station. It has been in a "battery box" on trickle-charge (using a charger with a "deep-cycle" setting) for most of the time since I bought it over a year ago, and it has been called on to supply power only a few times. Recently I noticed that the "fully charged" LED on the charger was not on and started investigating further. Having not encountered any batteries in the last few decades that have not been sealed and "maintenance free," I was surprised to find tiny print about checking the electrolyte level every 30 days -- but even then it took me a few minutes to figure out how to get access to the cells to check this. Anyway, when I removed the cunningly disguised covers, I found that the cells looked totally dry, and each took close to a pint of distilled water to bring the electrolyte level above the plates. The battery has now been on charge for about 20 hours at the charger's 12A setting, but most of the time the ammeter on the charger has shown only about 5A. The cells are all still gassing. Is this battery likely to come back to life again, or is it toast? Any remedial actions to take? The battery may be recoverable, but I suspect it's going to take some effort, and it may well have passed the point of no return. The fact that the cells are drawing low current, but are electrolyzing, suggests to me that you've got a combination of a high charge voltage (above 14.4) and some pretty badly sulphated plates. The bottom parts of the plates (where there was still some electrolyte) may be OK, while the upper portions may be sulphated and/or the separators may be clogged with solids. First thing I'd do, is just give it some time on the current setting, checking the electrolyte level periodically and refilling as necessary. Given some time, the relatively high voltage may clear out some of the sulphation and residue. If not, then it might be worth trying to recondition the battery. There are electrical desulphators available, which hit the battery with a high-voltage high-frequency pulse in order to break up and redissolve the sulphate crystals - some people say these work very well, others are less impressed. I've also seen chemical desulphation suggested, via the addition of some sort of chelation chemical (I *think* EDTA is used but don't trust that possibility without confirming it!). If some of the plate material has disintegrated and fallen to the bottom of the cell, then the battery is probably a goner. The residue can end up shorting the cell. -- Dave Platt AE6EO Hosting the Jade Warrior home page: http://www.radagast.org/jade-warrior I do _not_ wish to receive unsolicited commercial email, and I will boycott any company which has the gall to send me such ads! |
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