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Old March 21st 04, 11:05 PM
Bill Sloman
 
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John Woodgate wrote in message ...
I read in sci.electronics.design that Bill Sloman
wrote (in ) about 'CB
Radios, Cellphones and Gasoline Vapor Ignition', on Sun, 21 Mar 2004:
For the difference between Dewar benzene and Kekule benzene see

http://www.chemsoc.org/exemplarchem/...enzenering.htm


Dewar benzene can actually be made? Do you know when it was discovered?
What about the prismatic form? I would have thought that was a lot
easier to make, if I didn't have a suspicion that that is where simple
bonding ideas break down.


IIRR all three Dewar benzenes can be made - with difficulty.

They've been available since before 1971 at least - which is when my
project fell apart - but they were newish then.

The three-carbon rings at either end of the prismatic version do have
a lot of steric strain, but they can be made - I think pyrethroid
insecticides include just such a cyclopropane ring.

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Bill Sloman, Nijmegen
 
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