Agilent makes a bunch of possible detector diodes. For example, the
HSMS-2850 series of diodes suggests a sensitivity of "up to 35mV/uW"
at 2.45GHz. So with a 20dB coupler and 10mW (+10dBm) excitation, 40dB
return loss would give you about .3mV out of the detector, plenty to
see on a typical 3.5 digit digital voltmeter on a 200mV range. You'd
be lucky to get your coupler to have "40dB directivity" (that is,
calibrated that accurately to 50 ohms) anyway, unless you have a good
50 ohm precision load to check with. Be careful with such diodes:
they have a very low reverse voltage breakdown, so you shouldn't put
more than about +10dBm directly into a detector built with one of
them. But you can use other Schottky RF diodes with higher breakdown
if you really need to handle higher powers. The Agilent web site
should have selection guides to give you other ideas, if needed.