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"Jeff Liebermann" wrote in message
... On Fri, 23 Jan 2009 00:41:46 -0500, "Barry L. Ornitz" wrote: "Unless the resistors are protected by a coating that the fluid cannot permeate, such as an epoxy, these fluids cause the resistance of the Type AS resistors to increase. With some silicones, this increase is as little as 10%; with some mineral oils this can be as much as 100%. Generally, the resistance will rise as the fluid permeates the resistor body, and it will finally stabilize..." For a Carborundum resistor, if the mineral oil causes the resistance to increase, I would guess(tm) that it would corrode or otherwise remove material from the resistive element. That might [make] it a one way trip, where subsequent solvent cleaning, heating, and drying would probably not return the resistor to its original value. Doubling the value suggests that a considerable amount of material was corroded away. If the resistor material were [like] carbon composition [resistors], the mineral oil would act as an insulator between carbon grains, reducing the number of points of contact, and also increasing the resistance. However, this should be recoverable by cleaning and baking. Are either of these mechanisms probable? From what I know about the original Acheson Process and the later Lely and Modified Lely Processes for making silicon carbide, and about subsequent sintering processes, I suspect the true mechanism is somewhere in between the two extremes that Jeff suggests, but the second mechanism is more likely. Silicon carbide and graphite are quite inert to organic solvents. It would even take something like hydrofluoric acid to attack the material at such low temperatures. Knowing exactly how the material is sintered would help with the explanation. Three main methods of sintering silicon carbide are used. One uses glass frit or metal as a bonding agent. The second uses graphite and silicon metal which is reaction bonded to the silicon carbide grains. Finally boron carbide is used as a sintering aid for very high temperature applications. Since sintering only bonds a composite material in discrete points (as opposed to fully melting the material), an insulating liquid could diffuse between grains and increase the bulk resistance. Have you tried to "repair" the load resistor? No. Once I discovered that the transformer oil I had been given was contaminated with PCB's, I disposed of the Cantenna. The PCB containing oil was burned in an EPA-rated incinerator, and the Carborundum resistor was sent to a hazardous waste landfill. I had the original HN-31, so I rinsed the metal parts with solvent that was burned with the oil. I never tried washing the resistor, and I was afraid to vaporize the trapped mineral oil because of the PCB contamination. By this time, I had purchased a high power Bird termination load at a hamfest for $5. It had originally been used as a termination for a TACAN system and was marked accordingly with a metal plate stating that it was rated for a kilowatt in the frequency range of 900 to 1250 MHz. The seller had dropped the price in increments all day and yet hams were not interested thinking it would only work in that frequency range. I realized that this was a TEM and not a filled waveguide load and I got an exceptional deal. The seller had not bothered to read the resistance with an ohmmeter! Not wanting to pay Bird's high prices for a Type-N adapter, I made one myself. 73, Dr. Barry L. Ornitz WA4VZQ {transpose the digits to reply} |
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